Electrochemical Difunctionalization of gem-Difluoroalkenes: A Metal-Free Synthesis of α-Difluoro(alkoxyl/azolated) Methylated Ethers.
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DOI: 10.1021/acs.orglett.3c01130
Abstract: A scalable electrochemical difunctionalization of gem-difluoroalkenes to structurally versatile difluoro motifs was achieved. This methodology features reagent-free conditions, good functional group tolerance, and a relatively broad substrate scope. Meanwhile, the electrolysis protocol is easy to… read more here.
Keywords: difunctionalization gem; gem difluoroalkenes; difluoro; electrochemical difunctionalization ... See more keywords