Photoinduced Vicinal 1,2-Difunctionalization of Olefins for the Synthesis of Alkyl Sulfonamides.
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DOI: 10.1021/acs.orglett.3c00182
Abstract: Alkyl sulfonamides are an important class of bioactive molecules. Historical syntheses have relied on multistep sequences incorporating harsh reaction conditions. Photochemical methods have been limited to hydrosulfamoylation, installing only one substituent across an olefin. Herein,… read more here.
Keywords: alkyl sulfonamides; vicinal difunctionalization; photoinduced vicinal; difunctionalization olefins ... See more keywords
Intermolecular 1,2-difunctionalization of alkenes.
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DOI: 10.1039/d5cs00670h
Abstract: Alkenes are an important class of organic compounds with a carbon-carbon double bond and a wide range of industrial and natural sources. The presence of π bonds provides the possibility for many forms of transformations.… read more here.
Keywords: difunctionalization olefins; chemistry; intermolecular difunctionalization; difunctionalization alkenes ... See more keywords
Electrochemical iron-catalyzed difunctionalization of olefins: efficient and sustainable access to β-heteroarylated esters
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DOI: 10.1039/d5gc02319j
Abstract: Aliphatic esters are fundamental components of biologically active compounds and serve as flexible chemical intermediates in pharmaceutical synthesis. Yet, their preparation from readily accessible olefins has been fraught with challenges.... read more here.
Keywords: difunctionalization olefins; catalyzed difunctionalization; olefins efficient; iron catalyzed ... See more keywords