Haptotropic Phenomena in Digold(I) Triple-Bonded Complexes.
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DOI: 10.1021/acs.inorgchem.5c04642
Abstract: Addition of either IPrAuOTf or IPrCuOTf (IPr = 1,3-bis(2,6-diisopropylphenyl)imidazol-2-ylidene; OTf = trifluoromethanesulfonate anion) to the digold acetylide IPrAuC≡CAuIPr results in the selective formation of the corresponding trimetallic cationic species [IPrAuC≡C(π-MIPr)AuIPr][OTf] (M = Au or Cu).… read more here.
Keywords: digold triple; phenomena digold; bonded complexes; triple bonded ... See more keywords