Intermolecular dihydrogen bonding in VI, VII, and VIII group octahedral metal hydride complexes with water
Sign Up to like & getrecommendations! Published in 2018 at "Journal of Chemical Sciences"
DOI: 10.1007/s12039-018-1498-0
Abstract: The nature of dihydrogen bonding (DHB) in VI, VII, and VIII group octahedral metal hydride complexes with $$\hbox {H}_{2}\hbox {O}$$H2O has been studied systematically using quantum theory of atoms-in-molecule (QTAIM) analysis. A dihydrogen bond (H$$\cdots… read more here.
Keywords: hbox; dihydrogen bonding; dihydrogen; octahedral metal ... See more keywords
Ultrafast processes in photochromic material YHxOy studied by excited-state density functional theory simulation
Sign Up to like & getrecommendations! Published in 2020 at "Science China Materials"
DOI: 10.1007/s40843-020-1343-x
Abstract: Oxygen-containing rare-earth metal hydride, YHxOy, is a newly found photochromic material showing fast photoresponse. While its preparation method, optical properties and structural features have been studied extensively, the photochromic mechanism in YHxOy remains unknown. Here,… read more here.
Keywords: density functional; excited state; photochromic material; yhxoy ... See more keywords
Tuning the Nature and Formation of Bis(dihydrogen)–Osmium Species
Sign Up to like & getrecommendations! Published in 2018 at "Organometallics"
DOI: 10.1021/acs.organomet.7b00787
Abstract: The influence of chelate ligands in the formation and nature of bis(dihydrogen) units of OsH4 complexes has been studied. The classical trihydride OsH3{κ2-C,N-(C6H4-py)}(PiPr3)2 (1) reacts with HBF4·OEt2 to give the Kubas-type dihydrogen–elongated dihydrogen derivative [Os{κ2-C,N-(C6H4-py)}(η2-H2)2(PiPr3)2]BF4… read more here.
Keywords: pipr3 bf4; bis dihydrogen; nature; pipr3 ... See more keywords
Electroless Production of Fertilizer (Struvite) and Hydrogen from Synthetic Agricultural Wastewaters.
Sign Up to like & getrecommendations! Published in 2020 at "Journal of the American Chemical Society"
DOI: 10.1021/jacs.0c07916
Abstract: The drive toward sustainable phosphorus (P) recovery from agricultural and municipal wastewater streams has intensified. However, combining P recovery with energy conservation is perhaps one of the greatest challenges of this century. In this study,… read more here.
Keywords: fertilizer struvite; struvite hydrogen; electroless production; production fertilizer ... See more keywords
Zeolite-Encaged Isolated Platinum Ions Enable Heterolytic Dihydrogen Activation and Selective Hydrogenations.
Sign Up to like & getrecommendations! Published in 2021 at "Journal of the American Chemical Society"
DOI: 10.1021/jacs.1c09535
Abstract: Understanding the unique behaviors of atomically dispersed catalysts and the origin thereof is a challenging topic. Herein, we demonstrate a facile strategy to encapsulate Ptδ+ species within Y zeolite and reveal the nature of selective… read more here.
Keywords: dihydrogen; selective hydrogenations; activation; encaged isolated ... See more keywords
Decamethyltitanocene hydride intermediates in the hydrogenation of the corresponding titanocene-(η2-ethene) or (η2-alkyne) complexes and the effects of bulkier auxiliary ligands.
Sign Up to like & getrecommendations! Published in 2017 at "Dalton transactions"
DOI: 10.1039/c7dt01545c
Abstract: 1H NMR studies of reactions of titanocene [Cp*2Ti] (Cp* = η5-C5Me5) and its derivatives [Cp*(η5:η1-C5Me4CH2)TiMe] and [Cp*2Ti(η2-CH2[double bond, length as m-dash]CH2)] with excess dihydrogen at room temperature and pressures lower than 1 bar revealed the… read more here.
Keywords: bulkier auxiliary; hydrogenation; auxiliary ligands; alkyne complexes ... See more keywords