Intermolecular dihydrogen bonding in VI, VII, and VIII group octahedral metal hydride complexes with water
Sign Up to like & getrecommendations! Published in 2018 at "Journal of Chemical Sciences"
DOI: 10.1007/s12039-018-1498-0
Abstract: The nature of dihydrogen bonding (DHB) in VI, VII, and VIII group octahedral metal hydride complexes with $$\hbox {H}_{2}\hbox {O}$$H2O has been studied systematically using quantum theory of atoms-in-molecule (QTAIM) analysis. A dihydrogen bond (H$$\cdots… read more here.
Keywords: hbox; dihydrogen bonding; dihydrogen; octahedral metal ... See more keywords
Hydration of Nitriles Catalyzed by Ruthenium Complexes: Role of Dihydrogen Bonding Interactions in Promoting Base-Free Catalysis.
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DOI: 10.1021/acs.inorgchem.2c02058
Abstract: Ru(II) complexes of amide-phosphine-based tridentate ligands additionally containing pyridine, isoquinoline, and quinoline rings have been synthesized, and their catalytic utility for the selective hydration of nitriles to amides is explored under the base-containing as well… read more here.
Keywords: hydration nitriles; hydration; dihydrogen bonding; base free ... See more keywords
Impact of dihydrogen bonding on lattice energies and sublimation enthalpies of crystalline [H2GaNH2]3, [H2BNH2]3 and [H2GeCH2]3
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DOI: 10.1039/c9ra07144j
Abstract: Calculated lattice energies and sublimation enthalpies provide quantitative measures of the importance of intermolecular dihydrogen bonds. read more here.
Keywords: energies sublimation; sublimation enthalpies; lattice energies; dihydrogen bonding ... See more keywords