Neutral Bis(imino)-1,4-dihydropyridinate and Cationic Bis(imino)pyridine σ-Alkylzinc(II) Complexes as Hydride Exchange Systems: Classic Organometallic Chemistry Meets Ligand-Centered, Biomimetic Reactivity
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DOI: 10.1021/acs.organomet.8b00183
Abstract: The 1,4-dihydropyridinate complex [(4-Bn-HBIP)Zn(Bn)], readily available through the highly selective reaction of a 2,6-bis(imino)pyridine ligand with dibenzylzinc, contains two distinct reactive centers. One of them is the σ-organometallic benzylzinc moiety, which reacts with weak protic… read more here.
Keywords: bis imino; chemistry; pyridine; dihydropyridinate ... See more keywords