Ruthenium Complexes Bearing α-Diimine Ligands and Their Catalytic Applications in N-Alkylation of Amines, α-Alkylation of Ketones, and β-Alkylation of Secondary Alcohols
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DOI: 10.1021/acsomega.2c03200
Abstract: New Ru(II) complexes encompassing α-diimine ligands were synthesized by reacting ruthenium precursors with α-diimine hydrazones. The new ligands and Ru(II) complexes were analyzed by analytical and various spectroscopic methods. The molecular structures of L1 and… read more here.
Keywords: diimine ligands; ruthenium complexes; amines alkylation; alkylation ... See more keywords
Main-group metal complexes of α-diimine ligands: structure, bonding and reactivity.
Sign Up to like & getrecommendations! Published in 2021 at "Dalton transactions"
DOI: 10.1039/d1dt02120f
Abstract: α-Diimine ligands, in particular 1,4-diazabutadiene (dad) and bis(iminoacenaphthene) (bian) derivatives, have been widely used for coordination with various metals, including main-group, transition, and lanthanide and actinide metals. In addition to their tunable steric and electronic… read more here.
Keywords: diimine ligands; low valent; group metal; main group ... See more keywords