Recent advancements in α-diimine-nickel and -palladium catalysts for ethylene polymerization
Sign Up to like & getrecommendations! Published in 2021 at "European Polymer Journal"
DOI: 10.1016/j.eurpolymj.2021.110783
Abstract: Abstract The fascination of the well-defined metal catalysts for olefin polymerization is their capability to control the properties of the polymer such as topology (linear to highly branched), range of molecular weights and molecular weight… read more here.
Keywords: palladium catalysts; polymerization; ethylene polymerization; nickel palladium ... See more keywords
(α-Diimine)nickel Complexes That Contain Menthyl Substituents: Synthesis, Conformational Behavior, and Olefin Polymerization Catalysis
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DOI: 10.1021/acs.organomet.7b00283
Abstract: We describe the synthesis and coordination chemistry of the (1R,2S,5R)-menthyl-substituted N,N′-diaryl-α-diimine ligands N,N′-(2-Men-4-Me-Ph)2-BIAN (L1, Men = menthyl, BIAN = bis(imino)acenaphthene) and N,N′-(2-Men-4,6-Me2-Ph)2-BIAN (L2), the conformational properties of these ligands and their metal complexes, and the… read more here.
Keywords: polymerization; complexes contain; nickel complexes; contain menthyl ... See more keywords
Preparation and in situ chain-end-functionalization of branched ethylene oligomers by monosubstituted α-diimine nickel catalysts
Sign Up to like & getrecommendations! Published in 2019 at "Polymer Chemistry"
DOI: 10.1039/c9py00433e
Abstract: Chain-end-functionalization of (highly) branched ethylene oligomers was achieved in situ with the most/least bulky α-diimine nickel catalysts for the first time. read more here.
Keywords: chain end; nickel catalysts; end functionalization; diimine nickel ... See more keywords