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Published in 2023 at "Inorganic Chemistry"
DOI: 10.1021/acs.inorgchem.2c02340
Abstract: N,N′-Dialkylpiperazine-2,3-dithiones (R2pipdt) were recognized as a class of hexa-atomic cyclic dithiooxamide ligands with peculiar charge-transfer donor properties toward soft electron-acceptors such as noble metal cations and diiodine. The latter interaction is nowadays better described as…
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Keywords:
halogen;
mediated radical;
halogen bonding;
dithiooxamide ligands ... See more keywords
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1
Published in 2022 at "Frontiers in Chemistry"
DOI: 10.3389/fchem.2022.869110
Abstract: The Janus–faced ligand behavior of diiodine (I2) was evidenced after applying the dual descriptor (DD or second-order Fukui function), thus providing additional support to the work performed by Rogachev and Hoffmann in 2013. Along with…
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Keywords:
descriptor reveals;
dual descriptor;
janus faced;
diiodine ... See more keywords