H–H and N–H Bond Cleavages of Dihydrogen and Ammonia by a Bifunctional Imido (NH)-Bridged Diiridium Complex: A DFT Study
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DOI: 10.1021/acs.organomet.7b00581
Abstract: The mechanisms of H–H and N–H bond cleavages of dihydrogen and ammonia mediated by the diiridium μ2-imido complex [(Cp*Ir)2(μ2-H)(μ2-NH)]+ (A; Cp* = η5-C5Me5) were theoretically investigated with the density functional theory (DFT) method. Both oxidative… read more here.
Keywords: imido; bond; dihydrogen ammonia; cleavages dihydrogen ... See more keywords
Highly luminescent 2-phenylpyridine-free diiridium complexes with bulky 1,2-diarylimidazole cyclometalating ligands.
Sign Up to like & getrecommendations! Published in 2018 at "Dalton transactions"
DOI: 10.1039/c8dt04043e
Abstract: While a number of highly emissive dinuclear Ir(iii) complexes have been reported, they have generally been restricted to structures based on 2-phenylpyridine (Hppy) cyclometalates. We now present a series of new hydrazide-bridged diiridium complexes (5-8)… read more here.
Keywords: diarylimidazole cyclometalating; free diiridium; diiridium complexes; diiridium ... See more keywords
Pyridazine-bridged cationic diiridium complexes as potential dual-mode bioimaging probes† †Electronic supplementary information (ESI) available. See DOI: 10.1039/c8ra00265g
Sign Up to like & getrecommendations! Published in 2018 at "Rsc Advances"
DOI: 10.1039/c8ra00265g
Abstract: A novel cell permeable, mitochondria localising, diiridium complex has a high emission yield and two heavy atoms to increase scattering of electrons, supporting potential future applications as a dual fluorescence and electron microscopy probe. read more here.
Keywords: cationic diiridium; diiridium complexes; complexes potential; pyridazine bridged ... See more keywords