Construction and Reactivity of Benzimidazole‐Modified Thiolate‐Bridged Diiron Complexes with Different Electronic Structures
Sign Up to like & getrecommendations! Published in 2025 at "European Journal of Inorganic Chemistry"
DOI: 10.1002/ejic.202400643
Abstract: Thiolate‐bridged diiron complexes have drawn extensive attention due to their wide applications in the biomimetic simulation for the structure and function of various metalloenzymes and the related bioinspired catalysis. Through the introduction of the functional… read more here.
Keywords: thiolate bridged; bridged diiron; thiolate; electronic structures ... See more keywords
Toward Frameworks with Multiple Aligned and Interactive Fe(CO)3 Rotators: Syntheses and Structures of Diiron Complexes Linked by Two trans-Diaxial α,ω-Diphosphine Ligands Ar2P(CH2)nPAr2.
Sign Up to like & getrecommendations! Published in 2021 at "Inorganic chemistry"
DOI: 10.1021/acs.inorgchem.0c03737
Abstract: Reactions of (η4-benzylideneacetone)Fe(CO)3 and the α,ω-diphosphines Ar2P(CH2)nPAr2 afford the trigonal bipyramidal diiron tetraphosphorus complexes trans,trans-(CO)3Fe[Ar2P(CH2)nPAr2]2Fe(CO)3 (n/Ar = 3/Ph 3, 4/Ph 4a, 4/p-tol 4b; 56-19%). Crystal structures establish essentially parallel P-Fe-P axes, iron-iron distances of 5.894(9)-5.782(1)… read more here.
Keywords: diphosphine; ch2 npar2; ar2p ch2; diiron complexes ... See more keywords
Modulation of Fe-Fe distance and spin in diiron complexes using tetradentate ligands with different flanking donors.
Sign Up to like & getrecommendations! Published in 2024 at "Chemical communications"
DOI: 10.1039/d4cc02522a
Abstract: Here we report the synthesis and characterization of diiron complexes containing triaryl N4 and N2S2 ligands derived from o-phenylenediamine. The complexes display significant differences in Fe-Fe distances and magnetic properties that depend on the identity… read more here.
Keywords: complexes using; modulation distance; distance spin; spin diiron ... See more keywords
Bond Forming Reactions Involving Isocyanides at Diiron Complexes
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DOI: 10.3390/inorganics7030025
Abstract: The versatility of isocyanides (CNR) in organic chemistry has been tremendously enhanced by continuous advancement in transition metal catalysis. On the other hand, the urgent need for new and more sustainable synthetic strategies based on… read more here.
Keywords: reactions involving; isocyanides diiron; diiron complexes; bond forming ... See more keywords