Potent anticancer activity of photo-activated oxo-bridged diiron(III) complexes.
Sign Up to like & getrecommendations! Published in 2017 at "European journal of medicinal chemistry"
DOI: 10.1016/j.ejmech.2016.09.090
Abstract: Cancer-specific anticancer drugs are still an elusive goal. Using light as the temporal control to generate cytotoxic species from photo-activated prodrug in the presence or absence of molecular oxygen has shown potential application targeted chemotherapy… read more here.
Keywords: photo activated; diiron iii; chemistry; iii complexes ... See more keywords
New mechanistic insights into intramolecular aromatic ligand hydroxylation and benzyl alcohol oxidation initiated by the well-defined (μ-peroxo)diiron(iii) complex.
Sign Up to like & getrecommendations! Published in 2017 at "Chemical communications"
DOI: 10.1039/c7cc04382a
Abstract: A (μ-peroxo)diiron(iii) complex [Fe2(LPh4)(O2)(Ph3CCO2)]2+ (1-O2) with a dinucleating ligand (LPh4), generated from the reaction of a carboxylate bridged diiron(ii) complex [Fe2(LPh4)(Ph3CCO2)]2+ (1) with dioxygen in CH2Cl2, provides a diiron(iv)-oxo species as an active oxidant which… read more here.
Keywords: peroxo diiron; diiron iii; aromatic ligand; iii complex ... See more keywords
Catalytic and Stoichiometric Baeyer–Villiger Oxidation Mediated by Nonheme Peroxo-Diiron(III), Acylperoxo, and Iodosylbenzene Iron(III) Intermediates
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DOI: 10.3390/molecules27092814
Abstract: In this paper we describe a detailed mechanistic studies on the [FeII(PBO)2(CF3SO3)2] (1), [FeII(PBT)2(CF3SO3)2] (2), and [FeII(PBI)3](CF3SO3)2 (3)-catalyzed (PBO = 2-(2′-pyridyl)benzoxazole, PBT = 2-(2′-pyridyl)benzthiazole, PBI = 2-(2′-pyridyl)benzimidazole) Baeyer–Villiger oxidation of cycloketones by dioxygen with cooxidation… read more here.
Keywords: baeyer villiger; villiger oxidation; iii; diiron iii ... See more keywords
Effect of Redox Potential on Diiron-Mediated Disproportionation of Hydrogen Peroxide
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DOI: 10.3390/molecules28072905
Abstract: Heme and nonheme dimanganese catalases are widely distributed in living organisms to participate in antioxidant defenses that protect biological systems from oxidative stress. The key step in these processes is the disproportionation of H2O2 to… read more here.
Keywords: disproportionation; redox potential; diiron iii; benzimidazole ... See more keywords