Synthesis of Polysubstituted Germoles and Benzogermoles Using a Substoichiometric Amount of Diisobutylaluminum Hydride.
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DOI: 10.1021/acs.orglett.1c01314
Abstract: We developed a synthetic route to unsymmetrically polysubstituted germoles bearing different substituents from 1-hydrogermyl-4-silyl-1,3-enynes. The reaction proceeded with 0.5 equiv of diisobutylaluminum hydride. Various 2-silylgermoles including benzogermoles were obtained in good to excellent yields. 2-Germylbenzogermoles… read more here.
Keywords: diisobutylaluminum hydride; synthesis polysubstituted; benzogermoles using; polysubstituted germoles ... See more keywords