The unique β-diketiminate ligand in aluminum(i) and gallium(i) chemistry.
Sign Up to like & getrecommendations! Published in 2020 at "Dalton transactions"
DOI: 10.1039/c9dt04763h
Abstract: Over the past few decades, β-diketiminate ligands have been widely used in coordination chemistry and are capable of stabilizing various metal complexes in multiple oxidation states. Recently, the chemistry of aluminum and gallium in their… read more here.
Keywords: aluminum gallium; chemistry; diketiminate ligand;
Mg-Mg bond polarization induced by a superbulky β-diketiminate ligand.
Sign Up to like & getrecommendations! Published in 2020 at "Chemical communications"
DOI: 10.1039/d0cc05200k
Abstract: The bulk of a recently reported superbulky β-diketiminate ligand was further increased by introducing tBu substituents in the ligand backbone. Attempts to isolate free Mg radicals with this extremely bulky ligand failed. Instead, a dinuclear… read more here.
Keywords: superbulky diketiminate; ligand; bond polarization; diketiminate ligand ... See more keywords