Reactivity study of a β-diketiminate titanium(III) complex with a phosphanylphosphido ligand towards chlorophosphanes. A new method of synthesis of β-diketiminate titanium(IV) complexes with versatile phosphanylphosphinidenes
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DOI: 10.1016/j.poly.2019.04.051
Abstract: Abstract The reactivity of a β-diketiminate titanium(III) complex with a phosphanylphosphido ligand, [MeNacNacTi(Cl){η2-P(SiMe3)-PtBu2}] (1) (MeNacNac− = [Ar]NC(Me)CHC(Me)N[Ar]; Ar = 2,6-iPr2Ph), was investigated towards selected chlorophosphanes, such as tBu2PCl, iPr2PCl, Cy2PCl, (Cy)tBuPCl, (Me)tBuPCl, (Ph)tBuPCl, Ph2PCl, (iPr2N)tBuPCl and (Et2N)2PCl. The reactions… read more here.
Keywords: diketiminate titanium; menacnacti; tbupcl; titanium ... See more keywords