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Published in 2018 at "Dalton transactions"
DOI: 10.1039/c7dt04739h
Abstract: Diketone substrate bound nickel(ii) complexes of 2,6-bis(1-methylbenzimidazolyl)pyridine have been synthesized and characterized as relevant active site models for unusual diketone cleaving Ni(ii)-dependent enzymes Ni-ARD and DKDO. The average Ni-Npy/benzim bond distances (2.050-2.107 Å) of model…
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Keywords:
complexes ligand;
diketone;
ligand model;
nickel complexes ... See more keywords