Characterization of the solubilizing ability of short-chained glycol-grafted ammonium and phosphonium ionic liquids
Sign Up to like & getrecommendations! Published in 2020 at "Journal of Molecular Liquids"
DOI: 10.1016/j.molliq.2020.112786
Abstract: Abstract Infinite dilution activity coefficients and gas-to-liquid partition coefficients are reported for >40 organic solvents dissolved in (2-methoxyethyl) triethylphosphonium bis(trifluoromethylsulfonyl)imide, (2-methoxyethyl)tributylphosphonium bis(trifluoromethylsulfonyl)imide, and (2-methoxyethyl)triethylammonium bis(trifluoromethylsulfonyl)imide in the temperature range from 323.15 K to 373.15 K. Experimental values… read more here.
Keywords: infinite dilution; bis trifluoromethylsulfonyl; dilution activity; liquids characterization ... See more keywords
New Model to Predict Infinite Dilution Activity Coefficients Based on (∂p/∂x)T,x → 0
Sign Up to like & getrecommendations! Published in 2023 at "ACS Omega"
DOI: 10.1021/acsomega.3c00368
Abstract: Accurate prediction of infinite dilution activity coefficient (γ∞) is essential for the calculation of phase equilibria, solubility, and related properties in molecular thermodynamics. Here, we propose a new model to accurately predict the value of… read more here.
Keywords: dilution activity; infinite dilution; model; new model ... See more keywords