Construction of Heterometallic One‐Dimensional Chain with δ* in the HOMO Using Quadruple Hydrogen Bonds
Sign Up to like & getrecommendations! Published in 2024 at "European Journal of Inorganic Chemistry"
DOI: 10.1002/ejic.202400609
Abstract: Mixing [Rh2(acam)4] (acam = acetamidate) with pivalic acid yielded Head and Tail‐[Rh2(acam)2(OPiv)2] (1, where PivOH denotes pivalic acid). The highest occupied and lowest unoccupied molecular orbitals were determined through cyclic voltammetry, electron paramagnetic resonance of… read more here.
Keywords: acam; dimensional chain; hydrogen bonds; heterometallic one ... See more keywords
Copper(II)–ethylenediamine linked Nb24 dimer with one dimensional chain architecture
Sign Up to like & getrecommendations! Published in 2020 at "Inorganica Chimica Acta"
DOI: 10.1016/j.ica.2020.119646
Abstract: Abstract The one-pot synthesis of one-dimensional chain polyoxoniobate based on Nb24 building block, [{Cu(en)2(H2O)2}{Cu(en)2(H2O)}2(H2en)10][{(Nb24O72H6)[Cu(en)2]2}2Cu(en)2]·72H2O (1, en = ethylenediamine), are firstly presented. Compound 1 was structurally and compositionally characterized in the solid state by single-crystal X-ray diffraction, IR、UV… read more here.
Keywords: copper ethylenediamine; chain; one dimensional; dimensional chain ... See more keywords
From zero-dimensional to one-dimensional chain N-oxide bridged compounds with enhanced single-molecule magnetic performance.
Sign Up to like & getrecommendations! Published in 2019 at "Dalton transactions"
DOI: 10.1039/c9dt00210c
Abstract: A series of dinuclear dysprosium complexes bridged by pyridine-NO ligands with formula [Ln2(BTA)6(pyNO)2] (1Dy, Ln = Dy, 1Y, Ln = Y and 1Gd, Ln = Gd) (BTA = benzoyltrifluoroacetone, pyNO = pyridine-N-oxide) were structurally and… read more here.
Keywords: single molecule; one dimensional; dimensional chain; molecule magnetic ... See more keywords