Reductive Dimerization of Alkenes and Allenes Enabled by Photochemically Activated Zinc-Zinc Bonded Compounds.
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DOI: 10.1021/jacs.4c07390
Abstract: Metal radicals have shown versatile reactivity in modern synthetic chemistry. However, the use of zinc radicals for molecular synthesis has been barely explored. Here, we show that a transient zinc radical can be formed through… read more here.
Keywords: alkenes allenes; zinc zinc; dimerization alkenes; zinc ... See more keywords