Mixed azido/phenoxido bridged trinuclear Cu(ii) complexes of Mannich bases: Synthesis, structures, magnetic properties and catalytic oxidase activities.
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DOI: 10.1039/c8dt01400k
Abstract: Three similar Mannich base ligands viz. N,N-bis(3,5-dimethyl-2-hydroxybenzyl)-N',N'-dimethyl-1,3-diaminopropane (H2L1), N,N-bis(3,5-dimethyl-2-hydroxybenzyl)-N',N'-dimethyl-1,2-diaminoethane (H2L2) and N,N-bis(3,5-dimethyl-2-hydroxybenzyl)-N',N'-diethyl-1,2-diaminoethane (H2L3) upon reaction with Cu(CH3COO)2·H2O produced dinuclear complexes [Cu2L21-3]. The reaction of each of these isolated dimeric species with Cu(ClO4)2·6H2O and NaN3 resulted… read more here.
Keywords: dimethyl; dimethyl hydroxybenzyl; 2cu h2o; bis dimethyl ... See more keywords