Stabilization of Hydroxy Tautomeric Form of Dimethyl Phosphite in the Coordination Sphere of Carbonyl Complexes of Group VI Metals
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DOI: 10.1134/s1070363218090190
Abstract: The interaction of dimethyl phosphite with hexacarbonyls of the chromium group metals in a nonpolar solvent has afforded metal(0) σ4,λ4-(dimethyl phosphite)pentacarbonyls containing a hydroxy tautomeric form of dimethyl phosphite in the coordination sphere. Hydrogen of… read more here.
Keywords: dimethyl; hydroxy tautomeric; tautomeric form; dimethyl phosphite ... See more keywords
The Synthesis of α-Aminophosphonates via Enantioselective Organocatalytic Reaction of 1-(N-Acylamino)alkylphosphonium Salts with Dimethyl Phosphite
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DOI: 10.3390/molecules25020405
Abstract: α-Aminophosphonic acids are phosphorus analogues of α-amino acids. Compounds of this type find numerous applications in medicine and crop protection due to their unique biological activities. A crucial factor in these activities is the configuration… read more here.
Keywords: amino acids; acylamino; synthesis aminophosphonates; via enantioselective ... See more keywords