A Highly Active PBP–Iridium Catalyst for the Dehydrogenation of Dimethylamine–Borane: Catalytic Performance and Mechanism
Sign Up to like & getrecommendations! Published in 2017 at "ChemCatChem"
DOI: 10.1002/cctc.201700384
Abstract: A long‐tethered boron‐containing (P‐B‐P) pincer ligand with an aliphatic backbone was synthesized. Oxidative addition of the B−H bond in the ligand to [Ir(coe)2Cl]2 (coe=cyclooctene) afforded the (P‐B‐P)Ir(H)Cl complex. A catalyst system comprising the iridium complex… read more here.
Keywords: dehydrogenation; iridium; dimethylamine borane; performance ... See more keywords
Nanoalumina supported palladium(0) nanoparticle catalyst for releasing H2 from dimethylamine borane
Sign Up to like & getrecommendations! Published in 2019 at "Applied Surface Science"
DOI: 10.1016/j.apsusc.2019.05.087
Abstract: Abstract Palladium(II) 2,4-pentanedionate, impregnated on alumina nanopowder, was reduced by dimethylamine borane (DMAB) forming Pd(0) nanoparticles (NPs) at room temperature. Pd(0) NPs could be isolated from solution and characterized by ATR-IR, UV–vis, XRD, SEM, TEM,… read more here.
Keywords: palladium nanoparticle; borane; supported palladium; nanoalumina supported ... See more keywords
Gold nanoparticles as a catalyst for dehydrogenation reaction of dimethylamine borane at room temperature
Sign Up to like & getrecommendations! Published in 2020 at "International Journal of Hydrogen Energy"
DOI: 10.1016/j.ijhydene.2020.02.160
Abstract: Abstract In this work, active and stable catalyst for the dehydrogenation reaction of dimethylamine borane (DMAB) in solvent-free medium at room temperature has been prepared. The method is based on preparing in-situ monodispersed gold nanoparticles… read more here.
Keywords: reaction dimethylamine; microscopy; dimethylamine borane; room temperature ... See more keywords
Reactions of organoplatinum complexes with dimethylamine-borane
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DOI: 10.1039/d0nj03168b
Abstract: The reactions of dimethylamine-borane with platinum(II) or platinum(IV) triflate complexes gave, not the anticipated σ-complexes, but the respective hydridoplatinum complexes. The reaction with [Pt(OTf)Me3(NN)], with NN = 2,2′-bipyridine (bipy) and 4,4′-di-t-butyl-2,2′-bipyridine (bu2bipy), gave the rare… read more here.
Keywords: chmeco2me bipy; dimethylamine borane; hydridoplatinum complexes; bipy ... See more keywords
Metal-ligand cooperative κ1-N-pyrazolate Cp*RhIII-catalysts for dehydrogenation of dimethylamine-borane at room temperature.
Sign Up to like & getrecommendations! Published in 2021 at "Dalton transactions"
DOI: 10.1039/d1dt01705e
Abstract: 3,5-Dimethylpyrazole (Pz*H) in well-defined Cp*RhIII (Cp* = 1,2,3,4,5-pentamethylcyclopentadienyl) complexes, or as an additive to [Cp*RhCl2]2 enhances catalytic activity in the dehydrogenation of dimethylamine-borane (DMAB) at room-temperature. Mechanistic studies indicate that the Lewis acidic RhIII-centre and… read more here.
Keywords: rhiii; borane; dimethylamine borane; room temperature ... See more keywords