1-Dimethylamino-1-silacyclohexane: Synthesis, molecular structure and conformational behavior by gas-phase electron diffraction, Raman spectroscopy and detailed quantum chemical calculations
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DOI: 10.1016/j.molstruc.2018.08.076
Abstract: Abstract 1-(N,N-dimethylamino)-1-silacyclohexane 1 was synthesized. Contributions of the conformers of 1, Eq-trans: Eq-gauche: Ax-trans, were found to be 55(15):15(15):30(15) mol.% in gas phase at 288 K from gas electron diffraction. The enthalpy ΔH = 0.29(15) kcal/mol for Ax-to-Eq… read more here.
Keywords: gas; dimethylamino silacyclohexane; spectroscopy; raman spectroscopy ... See more keywords