Two Coordination Compounds Bearing Bis(2-dimethylaminoethyl) Ether: Syntheses, Crystal Structures and Catalytic Application to the Henry Reaction
Sign Up to like & getrecommendations! Published in 2018 at "Chemical Research in Chinese Universities"
DOI: 10.1007/s40242-018-7343-7
Abstract: Two novel coordination compounds, namely [Cu2(BDMAEE)(CH3COO)4] n (1) and [Ni(BDMAEE)Cl2](2) [BDMAEE=bis(2-dimethylaminoethyl) ether], have been synthesized and characterized by IR, elemental analysis, PXRD and X-ray single crystal diffraction. In compound 1, the central Cu(II) ion is… read more here.
Keywords: coordination compounds; henry reaction; geometry; reaction ... See more keywords
Directed Lithiation of Protected 4-Chloropyrrolopyrimidine: Addition to Aldehydes and Ketones Aided by Bis(2-dimethylaminoethyl)ether
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DOI: 10.3390/molecules28030932
Abstract: Pyrrolopyrimidines are important scaffolds for the preparation of bioactive molecules. Therefore, developing efficient and flexible ways for selective functionalization of the pyrrolopyrimidine skeleton is of interest. We have investigated lithiation-addition at C-6 of protected 4-chloro-7H-pyrrolo… read more here.
Keywords: lithiation; addition; dimethylaminoethyl ether; directed lithiation ... See more keywords