Stereochemistry and mechanism of oxidative 1,4-addition of trifluoroacetamide to 2,3-dimethylbuta-1,3-diene
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DOI: 10.1016/j.mencom.2017.05.026
Abstract: Oxidative addition of trifluoroacetamide to 2,3-dimethylbuta-1,3-diene leads to N , N’ -[(2 E )-2,3-dimethylbut-2-ene-1,4-diyl]bis(trifluoroacetamide) and [(2 RS ,3 SR )- N -(2,3-dihydroxy-4-iodo-2,3-dimethylbutyl)trifluoroacetamide. A tentative mechanism is proposed. read more here.
Keywords: oxidative addition; addition trifluoroacetamide; trifluoroacetamide dimethylbuta; dimethylbuta diene ... See more keywords