Supramolecular first-row transition metal complexes of 3-(3,5-dimethylpyrazol-1-yl)propanamide: Three different coordination modes
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DOI: 10.1016/j.poly.2019.02.056
Abstract: Abstract Michael addition of 3-tert-butylpyrazole (1) or 3,5-dimethylpyrazole (2) to acrylamide afforded the pyrazolylpropanamide-type ligands 3-(3-tert-pyrazol-1-yl)propanamide (3, = tBuPPA) and 3-(3,5-dimethylpyrazol-1-yl)propanamide (4, = Me2PPA), respectively, in high isolated yields (3: 80%, 4: 76%). Reactions of 4 with selected first-row… read more here.
Keywords: transition metal; three different; coordination; dimethylpyrazol propanamide ... See more keywords