Anti-addition of Dimethylsulfoxonium Methylide to Acyclic α,β-Unsaturated Ketones and Its Application in Formal Synthesis of an Eicosanoid
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DOI: 10.1021/acsomega.7b00663
Abstract: Cyclopropanation using dimethylsulfoxonium methylide (Corey–Chaykovsky reaction) was examined with a series of linear α,β-unsaturated ketones, and the results showed that the major trajectory for the addition of the sulfur ylide to the enones is anti,… read more here.
Keywords: unsaturated ketones; dimethylsulfoxonium methylide; formal synthesis; addition ... See more keywords