Theoretical Mechanistic Insights into Dinitrogen Activation by a Diniobium Tetrahydride: Two-State Reactivity and the Role of Potassium Cation Promoter.
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DOI: 10.1021/acs.inorgchem.9b03733
Abstract: A "two-state reactivity" scenario has been computationally disclosed for dinitrogen activation by a diniobium tetrahydride. Remarkably, it is revealed that alkali metal cations play a crucial role via alkali···N coordination interaction, which is capable of… read more here.
Keywords: dinitrogen activation; activation diniobium; diniobium tetrahydride; activation ... See more keywords