Theoretical mechanistic insights into dinitrogen cleavage by a dititanium hydride complex bearing PNP-pincer ligands.
Sign Up to like & getrecommendations! Published in 2021 at "Dalton transactions"
DOI: 10.1039/d1dt03852d
Abstract: The mechanism of dinitrogen cleavage by a PNP-coordinated dititanium polyhydride complex has been computationally investigated. A "multi-state reactivity" scenario has been disclosed for the whole process of N2 coordination and activation. Remarkably, the H2 elimination… read more here.
Keywords: cleavage; pnp pincer; dinitrogen cleavage;