EDA‐NOCV analysis of carbene‐borylene bonded dinitrogen complexes for deeper bonding insight: A fair comparison with a metal‐dinitrogen system
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DOI: 10.1002/jcc.26832
Abstract: Binding of dinitrogen (N2) to a transition metal center (M) and followed by its activation under milder conditions is no longer impossible; rather, it is routinely studied in laboratories by transition metal complexes. In contrast,… read more here.
Keywords: nocv analysis; eda nocv; dinitrogen complexes; dinitrogen ... See more keywords
Synthesis and Reactivity of Cobalt-Dinitrogen Complexes Bearing Anionic PCP-Type Pincer Ligands toward Catalytic Silylamine Formation from Dinitrogen.
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DOI: 10.1021/acs.inorgchem.2c00234
Abstract: A series of cobalt(I)-dinitrogen complexes bearing anionic 4-substituted benzene-based PCP-type pincer ligands are synthesized and characterized. These complexes work as highly efficient catalysts for the formation of silylamine from dinitrogen under ambient reaction conditions to… read more here.
Keywords: dinitrogen complexes; cobalt; bearing anionic; complexes bearing ... See more keywords
Dinitrogen Complexes of Cobalt(-I) Supported by Rare-Earth Metal-Based Metalloligands.
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DOI: 10.1021/acs.inorgchem.2c04099
Abstract: Sequential reactions of heptadentate phosphinoamine LH3 with rare-earth metal tris-alkyl precursor (Me3SiCH2)3Ln(THF)2 (Ln = Sc, Lu, Yb, Y, Gd) and a low-valent cobalt complex (Ph3P)3CoI afforded rare-earth metal-supported cobalt iodide complexes. Reduction of these iodide… read more here.
Keywords: earth metal; dinitrogen complexes; rare earth;
Development of catalytic nitrogen fixation using transition metal-dinitrogen complexes under mild reaction conditions.
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DOI: 10.1039/c8dt02572j
Abstract: This paper describes our recent progress in catalytic nitrogen fixation using transition metal-dinitrogen complexes as catalysts. Our research group has recently developed novel reaction systems for the catalytic transformation of molecular dinitrogen into ammonia and… read more here.
Keywords: dinitrogen; nitrogen fixation; dinitrogen complexes; reaction ... See more keywords
Tungsten and molybdenum dinitrogen complexes supported by a pentadentate tetrapodal phosphine ligand: comparative spectroscopic, electrochemical and reactivity studies.
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DOI: 10.1039/d1dt04212b
Abstract: The tungsten dinitrogen complex [W(N2)(PMe2PPPh2)] (2) (PMe2PPPh2 = [2-({bis[3-(diphenylphosphino)propyl]-phosphino}methyl)-2-methylpropane-1,3-diyl]bis(dimethylphosphine)) is synthesized and characterized by X-ray diffraction as well as IR and NMR spectroscopies, showing strong analogies to its molybdenum analogue [Mo(N2)(PMe2PPPh2)] (1). Whereas cyclic voltammetry… read more here.
Keywords: molybdenum dinitrogen; tungsten molybdenum; dinitrogen complexes; supported pentadentate ... See more keywords