Dinitrogen Reduction Coupled with Methanol Oxidation for Low Overpotential Electrochemical NH3 Synthesis Over Cobalt Pyrophosphate as Bifunctional Catalyst.
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DOI: 10.1002/smll.202208272
Abstract: Electrochemical dinitrogen (N2 ) reduction to ammonia (NH3 ) coupled with methanol electro-oxidation is presented in the current work. Here, methanol oxidation reaction (MOR) is proposed as an alternative anode reaction to oxygen evolution reaction… read more here.
Keywords: oxidation; dinitrogen reduction; nh3 synthesis;
Electroreduction of Nitrates, Nitrites, and Gaseous Nitrogen Oxides: A Potential Source of Ammonia in Dinitrogen Reduction Studies
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DOI: 10.1021/acsenergylett.0c00924
Abstract: The results presented herein unambiguously demonstrate that neither nanoparticulate carbon-supported gold, nor bismuth powder are active catalysts for the electrocatalytic dinitrogen reduction, but... read more here.
Keywords: dinitrogen; nitrates nitrites; electroreduction nitrates; nitrites gaseous ... See more keywords
Vanadium-Catalyzed Dinitrogen Reduction to Ammonia via a [V]═NNH2 Intermediate.
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DOI: 10.1021/jacs.2c08000
Abstract: The catalytic transformation of N2 to NH3 by transition metal complexes is of great interest and importance but has remained a challenge to date. Despite the essential role of vanadium in biological N2 fixation, well-defined… read more here.
Keywords: vanadium; vanadium catalyzed; catalyzed dinitrogen; reduction ... See more keywords
Nitrogenase resurrection and the evolution of a singular enzymatic mechanism
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DOI: 10.7554/elife.85003
Abstract: The planetary biosphere is powered by a suite of key metabolic innovations that emerged early in the history of life. However, it is unknown whether life has always followed the same set of strategies for… read more here.
Keywords: evolution singular; enzymatic mechanism; nitrogenase resurrection; mechanism ... See more keywords