Two Novel Dinuclear Cobalt Polypyridyl Complexes in Electro‐ and Photocatalysis for Hydrogen Production: Cooperativity Increases Performance
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DOI: 10.1002/cssc.202201049
Abstract: Abstract Syntheses and mechanisms of two dinuclear Co‐polypyridyl catalysts for the H2 evolution reaction (HER) were reported and compared to their mononuclear analogue (R1). In both catalysts, two di‐(2,2’‐bipyridin‐6‐yl)‐methanone units were linked by either 2,2’‐bipyridin‐6,6’‐yl… read more here.
Keywords: polypyridyl; novel dinuclear; dinuclear cobalt; production ... See more keywords
Dinuclear Cobalt Complexes for Homogeneous Water Oxidation: Tuning Rate and Overpotential Through the Non-Innocent Ligand.
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DOI: 10.1002/cssc.202201317
Abstract: In this study, dinuclear cobalt complexes ( 1 and 2 ) featuring bisbenzimidazolepyrazolide-type ligands ( H 2 L and Me 2 L ) were prepared and evaluated as molecular electrocatalysts for water oxidation. Notably, 1… read more here.
Keywords: water oxidation; water; dinuclear cobalt; rate ... See more keywords