Articles with "dinuclear complex" as a keyword



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Fluorogenic sulphate anion sensor with INHIBIT logic gate by dinuclear Zn (II) complex: Synthesis, emission, DFT studies

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Published in 2020 at "Inorganica Chimica Acta"

DOI: 10.1016/j.ica.2020.119794

Abstract: Abstract N4O3 coordinating heptadentate non emissive ligand emits strong blue emissive light only in the presence of Zn(II) ion. This ligand yields a solid crystalline μ-phenoxo bridge dinuclear Zn(II) complex 1a. The binding stoichiometry, binding… read more here.

Keywords: dinuclear complex; sulphate anion; logic gate; inhibit logic ... See more keywords
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X-ray crystal structure and theoretical study of a new dinuclear Cu(II) complex with two different geometry centers bridged with an oxo group

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Published in 2017 at "Journal of Molecular Structure"

DOI: 10.1016/j.molstruc.2017.06.024

Abstract: Abstract A new Schiff base ligand HL, 1,3-bis(2-((Z)-(2-aminoethylimino)methyl)phenoxy)ethylene di amine, has been synthesized from the reaction of a new aldehyde and ethylenediamine. After preparation the Schiff base, a new dinuclear Cu(II) complex with two different… read more here.

Keywords: dinuclear complex; new dinuclear; complex two; geometry ... See more keywords
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Synthesis and reactivity of hydride-bridged ruthenium dithiolene complexes

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Published in 2018 at "Polyhedron"

DOI: 10.1016/j.poly.2017.10.023

Abstract: Abstract Syntheses of two homonuclear hydride complexes, viz. hydride-bridged ruthenium dinuclear complex [Ru(η6-C6Me6)(S2C6H4)RuClH(PPh3)2] (3) and dihydride ruthenium dinuclear complex [Ru(η6-C6Me6)(S2C6H4) RuH2(PPh3)2] (4), have been described. Complex 4 was obtained as a mixture of cis- and… read more here.

Keywords: ruthenium; pph3; dinuclear complex; bridged ruthenium ... See more keywords
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Synthesis and structural characterization of a novel dinuclear Cu(ii) complex: an efficient and recyclable bifunctional heterogeneous catalyst for the diastereoselective Henry reaction.

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Published in 2018 at "Dalton transactions"

DOI: 10.1039/c8dt00708j

Abstract: We describe the synthesis and structural characterization of a novel dinuclear Cu(ii) complex containing a new flexible mixed pyridine-carboxylate ligand. Single crystal X-ray diffraction reveals its uniqueness with two coordinated water molecules and four uncoordinated… read more here.

Keywords: characterization novel; dinuclear complex; synthesis structural; structural characterization ... See more keywords
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Dinuclear Hg(II) complex of new benzimidazole-based Schiff base: one-pot synthesis, crystal structure, spectroscopy, and theoretical investigations

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Published in 2019 at "Journal of Coordination Chemistry"

DOI: 10.1080/00958972.2019.1680833

Abstract: Abstract A new dinuclear complex, [HgCl2L]2, was prepared using a Schiff base derived from benzimidazole (L = [1-(1H-benzo[d]imidazol-2-yl)-N-(4-methoxyphenyl)ethan-1-imine]. The mercury complex was obtained in good yield by one-pot reaction under microwave irradiation from 2-acetylbenzimidazole and… read more here.

Keywords: dinuclear complex; geometry; spectroscopy; one pot ... See more keywords