Articles with "dinuclear copper" as a keyword



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Anticandidal activity of hetero-dinuclear copper(II) Mn(II) Schiff base and its potential action of the mechanism

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Published in 2017 at "World Journal of Microbiology and Biotechnology"

DOI: 10.1007/s11274-017-2368-5

Abstract: Invasive fungal infections are one of the major challenges especially for immunosuppressed patients since they are drug resistant and pathogen to patients. Therefore, developing new, efficient and nonresistant antifungal agents have been a primary focus… read more here.

Keywords: anticandidal activity; hetero dinuclear; dinuclear copper; schiff base ... See more keywords
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Synthesis, structure, magnetic properties and DFT study of a dinuclear copper(II) macrocyclic complex containing acetate groups

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Published in 2021 at "Inorganica Chimica Acta"

DOI: 10.1016/j.ica.2021.120310

Abstract: Abstract Synthesis, spectroscopic characterizations and single crystal X-ray structure of a new dinuclear Copper(II) complex of the form [Cu2L(µ-O-OAc)(OAc)2](PF6) are reported. The molecular structure of the complex indicates that acetate ions coordinate to metals in… read more here.

Keywords: synthesis structure; dinuclear copper; structure; structure magnetic ... See more keywords
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Dinuclear copper(II) complexes of "end-off" bicompartmental ligands: Alteration of the chelating arms on ligands to regulate the reactivity of the complexes towards DNA.

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Published in 2019 at "Journal of inorganic biochemistry"

DOI: 10.1016/j.jinorgbio.2018.12.014

Abstract: Two phenol-based "end-off" biscompartmental heptadentate ligands were designed by introduction of substituents with different electronic and steric properties to the chelating arms, i.e. 2,6-bis{[(2-pyridylmethyl)(2-hydroxyethyl)amino]methyl}-4-methylphenol (L1) and 2,6-bis{[(2-aminoethyl)(2-hydroxyethyl)amino]methyl}-4-methylphenol (L2). The dinuclear copper(II) complexes (1 and 2)… read more here.

Keywords: copper complexes; cleavage; dinuclear copper; arms ligands ... See more keywords
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Dinuclear copper(II) complexes with derivative triazine ligands as biomimetic models for catechol oxidases and nucleases.

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Published in 2020 at "Journal of inorganic biochemistry"

DOI: 10.1016/j.jinorgbio.2020.111249

Abstract: The research reported herein focuses on the synthesis of two new Cu(II) complexes {[Cu2(2-X-4,6-bis(di-2-picolylamino)-1,3,5-triazine], with X = butane-1,4-diamine (2) or N-methylpyrenylbutane-1,4-diamine (3)}, the latter with a pyrene group as a possible DNA intercalating agent. The structure of… read more here.

Keywords: copper complexes; dna; triazine; dinuclear copper ... See more keywords
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Chloranilate bridged dinuclear copper(ii) complexes: syn–anti geometry tuned by the steric factor and supramolecular interactions

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Published in 2019 at "CrystEngComm"

DOI: 10.1039/c9ce00705a

Abstract: The anti-conformation of chloranilate bridged di-copper complexes of NNO donor Schiff-base ligands is more stable than the syn-conformation, but the latter is stabilised by CH⋯π and hydrogen bonding interactions between solvent of crystallisation and chloranilate… read more here.

Keywords: copper complexes; geometry; dinuclear copper; chloranilate bridged ... See more keywords
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Synthesis and reactivity of dinuclear copper(I) pyridine diimine complexes.

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Published in 2022 at "Dalton transactions"

DOI: 10.1039/d2dt02307e

Abstract: The reaction of a tethered pyridine diimine (PDI) ligand with copper(I) chloride yielded a μ-chlorido bridged cationic dicopper(I) PDI complex, which is a rare structural motif. The geometric constraint of the ligand is fostering attractive… read more here.

Keywords: reactivity dinuclear; dinuclear copper; diimine; synthesis reactivity ... See more keywords
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Structure and emission properties of dinuclear copper(i) complexes with pyridyltriazole

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Published in 2023 at "RSC Advances"

DOI: 10.1039/d2ra06986e

Abstract: A new series of five highly emissive binuclear heteroleptic pyridyltriazole-Cu(i)-phosphine complexes 1–5 was synthesized and examined by different experimental (IR, elemental and thermogravimetric analysis, single crystal X-ray diffraction technique, UV-vis and fluorescence spectroscopy) and quantum… read more here.

Keywords: dinuclear copper; properties dinuclear; structure emission; copper complexes ... See more keywords
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Chromotropism studies on copper(II) compounds. Part II. Dinuclear copper(II) complexes with triply-bridged hydroxo, acetate, and halo ligands

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Published in 2018 at "Journal of Coordination Chemistry"

DOI: 10.1080/00958972.2018.1506113

Abstract: Abstract Two triply-bridged dinuclear copper(II) complexes of formula [LCu(μ-OH)(μ-OAc)(μ-X)CuL]X⋅0.5H2O where L is a bidentate ligand of N-(pyridine-2-ylmethyl)propane-2-amine and X=Cl, 1 and Br, 2 were synthesized and characterized by elemental analyses, spectroscopic techniques (IR, UV–Vis, EPR),… read more here.

Keywords: copper complexes; copper; chromotropism studies; dinuclear copper ... See more keywords
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Dinuclear copper(I) complexes with substituted benzimidazole ligands. Synthesis and photo- and electroluminescent properties

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Published in 2017 at "Russian Journal of General Chemistry"

DOI: 10.1134/s1070363217050206

Abstract: New dinuclear copper(I) complexes with bridging bis-diimine ligands were synthesized on the basis of benzimidazole derivatives. The obtained complexes showed photo- and electroluminescent properties. Copper-containing emitters exhibited yellow, orange, and yellow–green electroluminescence with a maximum… read more here.

Keywords: photo electroluminescent; dinuclear copper; copper complexes; electroluminescent properties ... See more keywords