Mono- and Dinuclear Gold(I) Coumarin Complexes: Luminescence Studies and Singlet Oxygen Production.
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DOI: 10.1002/cplu.202300020
Abstract: The 4-(thiolmethyl)-7-(diethylamino)-2H-chromen-2-one ligand has been synthesized and used as chromophore in several mono- and dinuclear gold(I) compounds that contain a phosphane at the second coordination position. Four final products were able to obtain in pure… read more here.
Keywords: dinuclear gold; coumarin; mono dinuclear; gold ... See more keywords
Neutral dinuclear gold(I) complexes with N-phosphanyl, N-heterocyclic carbenes (NHCPs)
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DOI: 10.1016/j.jorganchem.2016.09.030
Abstract: Abstract Neutral dinuclear gold(I) complexes having general formula [Au 2 Cl 2 (NHCP)] (NHCP = N -phosphanyl N -heterocyclic carbene) have been synthesized by two different synthetic procedures: i) transmetalation of the NHCP ligand from the… read more here.
Keywords: neutral dinuclear; phosphanyl heterocyclic; gold; dinuclear gold ... See more keywords
Systematic investigation of the influence of electronic substituents on dinuclear gold(I) amidinates: synthesis, characterisation and photoluminescence studies.
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DOI: 10.1039/d1dt03795a
Abstract: Dinuclear gold(I) compounds are of great interest due to their aurophilic interactions that influence their photophysical properties. Herein, we showcase that gold-gold interactions can be influenced by tuning the electronic properties of the ligands. Therefore,… read more here.
Keywords: dinuclear gold; systematic investigation; investigation influence; gold ... See more keywords
Dinuclear gold(I) Complexes with Bidentate NHC Ligands as Precursors for Alkynyl Complexes via Mechanochemistry
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DOI: 10.3390/molecules27134317
Abstract: The use of alkynyl gold(I) complexes covers different research fields, such as bioinorganic chemistry, catalysis, and material science, considering the luminescent properties of the complexes. Regarding this last application, we report here the synthesis of… read more here.
Keywords: mechanochemistry; bidentate nhc; dinuclear gold; gold complexes ... See more keywords