Magnetic refrigeration property and slow magnetic relaxation behavior of five dinuclear Ln(III)-based compounds
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DOI: 10.1016/j.poly.2020.114938
Abstract: Abstract In this work, a series of dinuclear Ln(III)-based compounds with the molecular form [Ln2(L)2(dbm)2(H2O)2]·nCH3OH (Ln(III) = Eu (1) , Gd (2), Tb (3), Dy (4) and Ho (5), Hdbm = 1,3-diphenyl-1,3-propanedione and H2L =… read more here.
Keywords: refrigeration property; dinuclear iii; slow magnetic; magnetic refrigeration ... See more keywords
Chiral dinuclear Ln(iii) complexes derived from S- and R-2-(6-methoxy-2-naphthyl)propionate. Optical and magnetic properties.
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DOI: 10.1039/c8dt04149k
Abstract: The reaction of LnCl3·6H2O with (S)-(+)-2-(6-methoxy-2-naphthyl)propionic acid (S-HL), best known as naproxen, and 1,10-phenanthroline (phen) in EtOH allows the isolation of dinuclear chiral compounds S-1-4 of the formula [Ln2(S-L)6(phen)2]·3DMF·H2O [Ln(iii) = Eu (1), Gd (2),… read more here.
Keywords: iii; dinuclear iii; iii complexes; methoxy naphthyl ... See more keywords
Slow magnetic relaxation in dinuclear Co(III)-Co(II) complexes containing a five-coordinated Co(II) centre with easy-axis anisotropy.
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DOI: 10.1039/d2dt00857b
Abstract: Two air-stable Co(III)-Co(II) mixed-valence complexes of molecular formulas [CoIICoIII(L)(DMAP)3(CH3COO)]·H2O·CH3OH (1) and [CoIICoIII(L)(4-Pyrrol)3 (CH3COO)]·0.5CH2Cl2 (2) (H4L = 1,3-bis-(5-methyl pyrazole-3-carboxamide) propane; DMAP = 4-dimethylaminopyridine; and 4-Pyrrol = 4-pyrrolidinopyridine) were synthesized and characterized by single-crystal X-ray crystallography, high-field… read more here.
Keywords: dinuclear iii; five coordinated; iii; easy axis ... See more keywords