Near-infrared luminescence and magnetism of dinuclear lanthanide complexes constructed from a schiff-base and different β-diketonate coligands
Sign Up to like & getrecommendations! Published in 2021 at "Inorganica Chimica Acta"
DOI: 10.1016/j.ica.2021.120497
Abstract: Abstract Seven new dinuclear lanthanide complexes based on a schiff-base ligand H2L and β-diketonate coligands have been synthesized and characterized: [Eu2(acac)4(HL)2]·3C2H5OH (1), [Ln2(acac)2(HL)4]·6C2H5OH (Ln = Tb(2), Dy(3), Er(4), Yb(5)), [Dy2(bfa)4(HL)2]·2H2O (6), [Dy2(tmhd)2(HL)4] (7) (H2L =… read more here.
Keywords: infrared luminescence; near infrared; diketonate coligands; lanthanide complexes ... See more keywords
Structures, luminescent and magnetic properties of three dinuclear lanthanide complexes: Dysprosium compound displaying slow magnetic relaxation
Sign Up to like & getrecommendations! Published in 2019 at "Polyhedron"
DOI: 10.1016/j.poly.2018.10.046
Abstract: Abstract Three dinuclear lanthanide complexes: {[Ln2(L)2(tmhd)2(CH3OH)2]·nCH3OH} (Ln = Sm (1, n = 1), Eu (2, n = 0), Dy (3, n = 0); H2L = 2-hydroxy-N′-(2-hydroxy-3-methoxybenzylidene)benzohydrazide, tmhd = 2,2,6,6-tetramethylheptane-3,5-dione) were fabricated and structurally characterized. Compounds 1–3 are isostructural belonging to the tetragonal system with space group I4(1)/a.… read more here.
Keywords: slow magnetic; magnetic relaxation; three dinuclear; lanthanide complexes ... See more keywords
Modulation of the properties of dinuclear lanthanide complexes through utilizing different β-diketonate co-ligands: near-infrared luminescence and magnetization dynamics.
Sign Up to like & getrecommendations! Published in 2020 at "Dalton transactions"
DOI: 10.1039/c9dt04093e
Abstract: A family of new dinuclear lanthanide complexes as the simplest entities showing intramolecular magnetic interactions, [Ln2(dbm)2(L)2(CH3OH)2] (Ln = Tb (1), Dy (2), Ho (3), Er (4), Yb (5), Lu (6)), [Ln2(acac)2(L)2(EtOH)2] (Ln = Dy (7),… read more here.
Keywords: diketonate ligands; lanthanide complexes; dinuclear lanthanide; magnetization ... See more keywords
Characteristic stacked structures and luminescent properties of dinuclear lanthanide complexes with pyrene units
Sign Up to like & getrecommendations! Published in 2023 at "Frontiers in Chemistry"
DOI: 10.3389/fchem.2023.1154012
Abstract: A novel design strategy of stacked organic fluorophores using dinuclear lanthanide (Ln(III)) complexes is demonstrated for the formation of excimer. The dinuclear Ln(III) complexes are composed of two Ln(III) (Eu(III) or Gd(III)) ions, six hexafluoroacetylacetonate… read more here.
Keywords: dinuclear lanthanide; luminescent properties; iii; stacked structures ... See more keywords