Mono- and dinuclear mimics of the [FeFe] hydrogenase enzyme featuring bis(monothiolato) and 1,3,5-triaza-7-phosphaadamantane ligands
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DOI: 10.1016/j.ica.2020.119442
Abstract: Abstract Two new complexes [Fe2(µ-SC6H4CH3-p)2(CO)5(PTA)] 1 and [Fe(κ1-SC6H4CH3-p)2(CO)2(PTA)2] 2 with bis(monothiolato) ligands, resembling the active site of iron hydrogenases have been synthesized and analyzed for proton reduction activity using cyclic voltammetric techniques. The structure and… read more here.
Keywords: mono dinuclear; mimics fefe; dinuclear mimics; bis monothiolato ... See more keywords