A dinuclear nickel catalyst based on metal–metal cooperation for electrochemical hydrogen production
Sign Up to like & getrecommendations! Published in 2020 at "Inorganica Chimica Acta"
DOI: 10.1016/j.ica.2020.119498
Abstract: Abstract In the quest for efficient metal catalysts for hydrogen production, a new dinuclear nickel complex of formula [{(μ-2-thiazolethiolate)Ni(1,3-bis(diphenylphosphino)propane)}2](BF4)2 (2) has been synthesized. Complex 2 shows electrochemical catalytic behavior for hydrogen production with a overpotential… read more here.
Keywords: metal; hydrogen production; dinuclear nickel; cooperation ... See more keywords
Recent advances of dinuclear nickel- and palladium-complexes in homogeneous catalysis.
Sign Up to like & getrecommendations! Published in 2020 at "Chemical communications"
DOI: 10.1039/d0cc02542a
Abstract: The development of dinuclear transition metal catalysis has gained considerable momentum in recent years. The synergistic interaction between two metals enables the development of dinuclear metal catalysts with high efficiency, robustness and uniqueness. In this… read more here.
Keywords: dinuclear nickel; palladium complexes; catalysis; advances dinuclear ... See more keywords
Urea Decomposition Mechanism by Dinuclear Nickel Complexes
Sign Up to like & getrecommendations! Published in 2023 at "Molecules"
DOI: 10.3390/molecules28041659
Abstract: Urease is an enzyme containing a dinuclear nickel active center responsible for the hydrolysis of urea into carbon dioxide and ammonia. Interestingly, inorganic models of urease are unable to mimic its mechanism despite their similarities… read more here.
Keywords: dinuclear nickel; nickel complexes; urea decomposition; mechanism ... See more keywords