Dinuclear Silver Complexes for Solvent-Free Catalytic Synthesis of Cyclic Carbonates from Epoxides and CO2 at Ambient Temperature and Pressure
Sign Up to like & getrecommendations! Published in 2018 at "Catalysis Letters"
DOI: 10.1007/s10562-017-2268-1
Abstract: AbstractA well structure-defined dinuclear silver complex [Ag2(PDP)]OTf, where HPDP—bispyridylpyrrole ligand, OTf−—triflato, was used as catalyst for coupling of CO2 with epoxides to generate exclusive cyclic carbonates. Yield up to 87% was obtained for various substrates… read more here.
Keywords: dinuclear silver; silver; ambient temperature; temperature pressure ... See more keywords
Dinuclear silver(I)-N-heterocyclic carbene complexes: Synthesis, characterization and larvicidal activity of bis-imidazolium dinuclear silver(I)-N-heterocyclic carbene complexes.
Sign Up to like & getrecommendations! Published in 2017 at "Journal of inorganic biochemistry"
DOI: 10.1016/j.jinorgbio.2017.07.030
Abstract: New synthesized bis-imidazolium salts that are linked by xylyl derivatives moiety, 1-4 was reacted with Ag2O to facilitate the formation of dinuclear Ag(I)-N-heterocyclic carbene (NHC) complexes, 5-8, respectively. All the synthesized ligand salts and complexes… read more here.
Keywords: carbene complexes; dinuclear silver; silver heterocyclic; imidazolium ... See more keywords
Dinuclear silver(I)- and gold(I)-N-heterocyclic carbene complexes of N-alkyl substituted bis-benzimidazol-2-ylidenes with aliphatic spacer: Synthesis, characterizations and antibacterial studies
Sign Up to like & getrecommendations! Published in 2021 at "Journal of Molecular Structure"
DOI: 10.1016/j.molstruc.2021.131187
Abstract: Abstract New series of dinuclear Ag(I)-NHC and Au(I)-NHC complexes (NHC = N-heterocyclic carbene) bearing n-alkyl homologous series with propylene spacers were synthesized. Initially, bis-benzimidazolium salts, 1-5 were synthesized via two steps n-alkylation reaction. The salts were then… read more here.
Keywords: antibacterial studies; nhc complexes; coli aureus; heterocyclic carbene ... See more keywords
Visible Light Absorption and Long-Lived Excited States in Dinuclear Silver(I) Complexes with Redox-Active Ligands.
Sign Up to like & getrecommendations! Published in 2020 at "Inorganic chemistry"
DOI: 10.1021/acs.inorgchem.0c02938
Abstract: Well-defined dinuclear silver(I) complexes have been targeted for applications in catalysis and materials chemistry, and the effect of close silver-silver interactions on electronic structure remains an area of active inquiry. In this study, we describe… read more here.
Keywords: absorption; dinuclear silver; silver complexes; chemistry ... See more keywords