Atroposelective Synthesis of C-C Axially Chiral Compounds via Mono- and Dinuclear Vanadium Catalysis.
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DOI: 10.1021/acs.accounts.2c00545
Abstract: ConspectusAxially chiral compounds with rotationally constrained σ-bonds that exhibit atropisomerism are lucrative synthetic targets because of their ubiquity in functional materials and natural products. The metal complex-catalyzed enantioselective fabrication of axially chiral scaffolds has been… read more here.
Keywords: vanadium; dinuclear vanadium; reaction; mono dinuclear ... See more keywords