Water soluble dinuclear zinc(II) complex based sensor for pyrophosphate anion under indicator displacement assays
Sign Up to like & getrecommendations! Published in 2019 at "Polyhedron"
DOI: 10.1016/j.poly.2019.06.027
Abstract: Abstract In this study, we synthesized a new water soluble dinuclear zinc(II) complex, ZnL3, for detection of PPi under indicator displacement assay by using pyrocatechol violet (PV) as sensing indicator. After addition of various anions… read more here.
Keywords: soluble dinuclear; dinuclear zinc; water soluble; indicator ... See more keywords
Catalytic Asymmetric Umpolung Tandem Reactions of Hemiacetals via Dinuclear Zinc Cooperative Catalysis.
Sign Up to like & getrecommendations! Published in 2022 at "Organic letters"
DOI: 10.1021/acs.orglett.2c00913
Abstract: The umpolung activity of hemiacetals serving as α-carbon nucleophiles has been reported via dinuclear zinc cooperative catalysis. This umpolung strategy has been applied to catalytic asymmetric tandem reactions of 1-tosylindoline-2,3-diols with β,γ-unsaturated-α-keto compounds, providing a… read more here.
Keywords: dinuclear zinc; tandem reactions; cooperative catalysis; via dinuclear ... See more keywords
On the importance of RH3C⋯N tetrel bonding interactions in the solid state of a dinuclear zinc complex with a tetradentate Schiff base ligand
Sign Up to like & getrecommendations! Published in 2021 at "CrystEngComm"
DOI: 10.1039/d0ce01864c
Abstract: The tetrel bonding and π-stacking interactions in a new dinuclear zinc complex using a tetradentate N2O2 donor Schiff base have been analysed energetically using DFT calculations and several computational tools. read more here.
Keywords: schiff base; tetrel bonding; zinc complex; dinuclear zinc ... See more keywords
Dinuclear zinc-catalyzed asymmetric Friedel-Crafts alkylation/cyclization of 3-aminophenols with α,α-dicyanoolefins.
Sign Up to like & getrecommendations! Published in 2021 at "Chemical communications"
DOI: 10.1039/d1cc04177k
Abstract: An enantioselective Friedel-Crafts alkylation/cyclization tandem reaction of 3-aminophenols with α,α-dicyanoolefins has been performed successfully using a chiral dinuclear zinc catalyst, leading to a range of chiral 2-amino-4H-chromenes (up to 98% yield and >99% ee). To… read more here.
Keywords: crafts alkylation; aminophenols dicyanoolefins; dinuclear zinc; zinc ... See more keywords