NO Generation from the Cross-Talks between Ene-diol Antioxidants and Nitrite at Metal Sites.
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DOI: 10.1021/acs.inorgchem.2c00364
Abstract: The one-electron reduction of nitrite (NO2-) to nitric oxide (NO) and ene-diol oxidation are two important biochemical transformations. Employing mononuclear cobalt-nitrite complexes with CoIII and CoII oxidation states, [(Bz3Tren)CoIII(nitrite)2](ClO4) (1) and [(Bz3Tren)CoII(nitrite)](ClO4) (2), this report… read more here.
Keywords: diol antioxidants; oxidation; metal sites; generation ... See more keywords