Transition-Metal-Free Stereocomplementary Cross-Coupling of Diols with Boronic Acids as Nucleophiles.
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DOI: 10.1021/acs.orglett.7b03192
Abstract: The transition-metal-free diastereoselective C(sp2)-C(sp3) cross-coupling between unprotected diols and boronic acids or potassium organotrifluoroborates is reported. Depending on the reaction conditions, the syn or the anti reaction products are obtained in a stereocomplementary fashion. This… read more here.
Keywords: boronic acids; transition metal; diols boronic; metal free ... See more keywords