Structures of three disubstituted [13]-macrodilactones reveal effects of substitution on macrocycle conformation
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DOI: 10.1107/s2056989020012037
Abstract: The synthesis and crystal structures of three new disubstituted [13]-macrodilactones, trans-4,8-dimethyl-1,10-dioxacyclotridec-5-ene-2,9-dione, cis-4-(4-bromophenyl)-13-methyl-1,10-dioxacyclotridec-5-ene-2,9-dione, and trans-11-methyl-4-phenyl-1,10-dioxacyclotridec-5-ene-2,9-dione are reported and their conformations are put in the context of other [13]-macrodilactone structures reported previously, showing that the number, location,… read more here.
Keywords: dioxacyclotridec ene; structures three; three disubstituted; disubstituted macrodilactones ... See more keywords