Confined Growth of Silver–Copper Janus Nanostructures with {100} Facets for Highly Selective Tandem Electrocatalytic Carbon Dioxide Reduction
Sign Up to like & getrecommendations! Published in 2022 at "Advanced Materials"
DOI: 10.1002/adma.202110607
Abstract: Electrocatalytic carbon dioxide reduction reaction (CO2RR) holds significant potential to promote carbon neutrality. However, the selectivity toward multicarbon products in CO2RR is still too low to meet practical applications. Here the authors report the delicate… read more here.
Keywords: carbon; 100 facets; carbon dioxide; dioxide reduction ... See more keywords
Effects of substrate porosity in carbon aerogel supported copper for electrocatalytic carbon dioxide reduction
Sign Up to like & getrecommendations! Published in 2019 at "Electrochimica Acta"
DOI: 10.1016/j.electacta.2018.11.203
Abstract: Abstract Despite the vast number of carbon-supported catalysts in industrial processes, the relationship between the active catalyst and the carbon framework is not well understood. In this study, we report the importance of the carbon… read more here.
Keywords: dioxide reduction; porosity; carbon dioxide; porosity carbon ... See more keywords
Porphyrin Coordination Polymer with Dual Photocatalytic Sites for Efficient Carbon Dioxide Reduction.
Sign Up to like & getrecommendations! Published in 2022 at "ACS applied materials & interfaces"
DOI: 10.1021/acsami.1c23941
Abstract: The resurgence of visible light photocatalysis for carbon dioxide reduction reaction (CO2RR) has resulted in the generation of various homogeneous and heterogeneous paradigms. Herein, a new system has been established by incorporating dual catalytic sites… read more here.
Keywords: dioxide reduction; carbon dioxide; microscopy; coordination polymer ... See more keywords
Hydrogenative Carbon Dioxide Reduction Catalyzed by Mononuclear Ruthenium Polypyridyl Complexes: Discerning between Electronic and Steric Effects
Sign Up to like & getrecommendations! Published in 2017 at "ACS Catalysis"
DOI: 10.1021/acscatal.7b00603
Abstract: The preparation and isolation of a family of Ru–Cl complexes containing the deprotonated anionic tridentate meridional ligand (1Z,3Z)-N1,N3-di(pyridin-2-yl)isoindoline-1,3-diimine (Hbid) and 1,3-di(2-pyridyl)benzene) (Hdpb), namely, [Ru(bid)(acac)Cl], 1d, [Ru(bid)(6,6′-Me2-bpy)Cl], 1e, trans-[Ru(bid)(py)2Cl], 2, [Ru(dpb)(bpy)Cl], 3a, and [Ru(dpb)(4,4′-(COOEt)2-bpy)Cl], 3b, are… read more here.
Keywords: dioxide reduction; reduction; catalyzed mononuclear; hydrogenative carbon ... See more keywords
Understanding trends in electrochemical carbon dioxide reduction rates
Sign Up to like & getrecommendations! Published in 2017 at "Nature Communications"
DOI: 10.1038/ncomms15438
Abstract: Electrochemical carbon dioxide reduction to fuels presents one of the great challenges in chemistry. Herein we present an understanding of trends in electrocatalytic activity for carbon dioxide reduction over different metal catalysts that rationalize a… read more here.
Keywords: electrochemical carbon; reduction; dioxide reduction; carbon ... See more keywords
Recent advances in single atom catalysts for the electrochemical carbon dioxide reduction reaction
Sign Up to like & getrecommendations! Published in 2021 at "Chemical Science"
DOI: 10.1039/d1sc01375k
Abstract: The electrochemical carbon dioxide reduction reaction (CO2RR) offers a promising solution to mitigate carbon emission and at the same time generate valuable carbonaceous chemicals/fuels. Single atom catalysts (SACs) are encouraging to catalyze the electrochemical CO2RR… read more here.
Keywords: electrochemical carbon; dioxide reduction; carbon; carbon dioxide ... See more keywords
Carbon dioxide reduction by an Al–O–P frustrated Lewis pair
Sign Up to like & getrecommendations! Published in 2022 at "Chemical Science"
DOI: 10.1039/d2sc01870e
Abstract: The reaction of tBu2P(O)H with Bis2AlH (Bis = CH(SiMe3)2) afforded the adduct tBu2P(H)–O–Al(H)Bis2 (3). It slowly releases H2 to form the first oxygen-bridged geminal Al/P frustrated Lewis pair tBu2P–O–AlBis2. It is capable of reversibly binding… read more here.
Keywords: lewis pair; frustrated lewis; carbon dioxide; reduction frustrated ... See more keywords
Boosting Electrochemical Carbon Dioxide Reduction on Atomically Dispersed Nickel Catalyst
Sign Up to like & getrecommendations! Published in 2021 at "Frontiers in Chemistry"
DOI: 10.3389/fchem.2021.837580
Abstract: Single-atom catalysts (SACs) with metal–nitrogen (M–N) sites are one of the most promising electrocatalysts for electrochemical carbon dioxide reduction (ECO2R). However, challenges in simultaneously enhancing the activity and selectivity greatly limit the efficiency of ECO2R… read more here.
Keywords: electrochemical carbon; carbon dioxide; carbon; dioxide reduction ... See more keywords