Redox-Neutral Transformations of Carbon Dioxide Using Coordinatively Unsaturated Late Metal Silyl Amide Complexes.
Sign Up to like & getrecommendations! Published in 2022 at "Inorganic chemistry"
DOI: 10.1021/acs.inorgchem.2c03453
Abstract: Two-coordinate silylamido complexes of nickel and copper rapidly react with CO2 to selectively form a new cyanate ligand along with hexamethyldisiloxane byproducts. Mechanistic insight into these reactions was obtained from the synthesis of proposed intermediates,… read more here.
Keywords: carbon dioxide; dioxide using; neutral transformations; redox neutral ... See more keywords
Catalytic Reduction of Carbon Dioxide Using Cationic Organoaluminum and -Gallium Compounds
Sign Up to like & getrecommendations! Published in 2017 at "Organometallics"
DOI: 10.1021/acs.organomet.7b00716
Abstract: Ethide abstraction from Et3M (M = Al and Ga), (2,6-Ph2C6H3)AlEt2, 1, and (2,6-Dipp2C6H3)GaEt2, 2 (Dipp = 2,6-iPr2C6H3), using the silylium ion [Et3Si][CHB11Cl11] afforded crystalline ion-like compounds [Et2M][CHB11Cl11] (M = Al, 3; Ga, 5) and [(2,6-Ph2C6H3)AlEt][CHB11Cl11],… read more here.
Keywords: catalytic reduction; reduction; carbon dioxide; gallium ... See more keywords