Dioxidomolybdenum(VI) complexes of tridentate ONO donor aroylhydrazones: Syntheses, spectral and structural characterization
Sign Up to like & getrecommendations! Published in 2017 at "Polyhedron"
DOI: 10.1016/j.poly.2016.11.033
Abstract: Abstract Four dioxidomolybdenum(VI) complexes, [MoO2(L1)(H2O)] (1), [MoO2(L1)(H2O)]·(4,4′-bipy) (2), [(MoO2(L1))2(4,4′-bipy)]·2H2O (3) and [MoO2(L2)(DMF)] (4), of two tridentate ONO donor aroylhydrazones, H2L1 and H2L2 (where H2L1 = 3-methoxy-2-hydroxybenzaldehyde-2-furoic acid hydrazone and H2L2 = 4-benzyloxy-2-hydroxybenzaldehyde-4-nitrobenzoic hydrazone), have been synthesized and characterized by… read more here.
Keywords: tridentate ono; moo2; donor aroylhydrazones; moo2 h2o ... See more keywords
Oxygen Atom Transfer Catalysis by Dioxidomolybdenum(VI) Complexes of Pyridyl Aminophenolate Ligands
Sign Up to like & getrecommendations! Published in 2021 at "Polyhedron"
DOI: 10.1016/j.poly.2021.115234
Abstract: Abstract A series of new cationic dioxidomolybdenum(VI) complexes [MoO2(Ln)]PF6 (2-5) with the tripodal tetradentate pyridyl aminophenolate ligands HL2-HL5 have been synthesized and characterized. Ligands HL2-HL4 carry substituents in the 4-position of the phenolate ring, viz.… read more here.
Keywords: aminophenolate ligands; atom transfer; oxygen atom; pyridyl aminophenolate ... See more keywords
Oxygen atom transfer between DMSO and benzoin catalyzed by cis-dioxidomolybdenum(VI) complexes of tetradentate Mannich bases
Sign Up to like & getrecommendations! Published in 2018 at "New Journal of Chemistry"
DOI: 10.1039/c7nj03551a
Abstract: The reaction of dibasic tetradentate ONNO donor Mannich bases derived from ethylenediamine and 2,4-di-tert-butylphenol (H2L1I), 2,4-di-methylphenol (H2L2II), 2-tert-butyl-4-methylphenol (H2L3III), 2,4-di-chlorophenol (H2L4IV) and 2-naphthol (H2L5V) with [MoVIO2(acac)2] (Hacac = acetylacetone) in a 1 : 1 molar ratio in… read more here.
Keywords: oxygen atom; mannich bases; movio2; cis dioxidomolybdenum ... See more keywords