Photocatalytic Oxygenation Reactions Using Water and Dioxygen.
Sign Up to like & getrecommendations! Published in 2019 at "ChemSusChem"
DOI: 10.1002/cssc.201901276
Abstract: Water (H₂O) is the most environmentally benign reductant that is oxidized to evolve dioxygen (O₂) in photosystem II, whereas dioxygen is the greenest oxidant. This minireview focuses on photocatalytic oxygenation of substrates using H₂O as… read more here.
Keywords: water; dioxygen; oxygenation substrates; water dioxygen ... See more keywords
Reactivity of organoplatinum complexes containing appended alcohol functional groups: Activation of dioxygen and hydrogen peroxide
Sign Up to like & getrecommendations! Published in 2017 at "Journal of Organometallic Chemistry"
DOI: 10.1016/j.jorganchem.2016.11.027
Abstract: Abstract The oxidative addition reactions of platinum(II) complexes [PtMe 2 (RN=CH-2-C 5 H 4 N)], especially when R = CH 2 CH 2 OH or CH 2 CH 2 CH 2 OH, have been studied. Both complexes… read more here.
Keywords: organoplatinum complexes; hydrogen; hydrogen peroxide; reactivity organoplatinum ... See more keywords
Recent progress in production and usage of hydrogen peroxide
Sign Up to like & getrecommendations! Published in 2021 at "Chinese Journal of Catalysis"
DOI: 10.1016/s1872-2067(20)63767-6
Abstract: Abstract Hydrogen peroxide has attracted increasing interest as an environmentally benign and green oxidant that can also be used as a solar fuel in fuel cells. This review focuses on recent progress in production of… read more here.
Keywords: dioxygen; hydrogen; production; hydrogen peroxide ... See more keywords
Selective Control and Characteristics of Water Oxidation and Dioxygen Reduction in Environmental Photo(electro)catalytic Systems
Sign Up to like & getrecommendations! Published in 2023 at "Accounts of Chemical Research"
DOI: 10.1021/acs.accounts.3c00002
Abstract: Conspectus Employing semiconductor materials is a popular engineering method to harvest solar energy, which is widely investigated for photocatalysis (PC) and photoelectrocatalysis (PEC) that convert solar light to chemical energy. In particular, environmental photo(electro)catalysis has… read more here.
Keywords: dioxygen; water oxidation; water dioxygen; water ... See more keywords
Symmetry-Adapted Synthesis of Dicopper Oxidases with Divergent Dioxygen Reactivity.
Sign Up to like & getrecommendations! Published in 2022 at "Inorganic chemistry"
DOI: 10.1021/acs.inorgchem.2c01898
Abstract: Artificial metalloenzymes have fed our understanding of how inorganic reactivities emerge, evolve, and diversify in protein environments. Herein, we created dinuclear copper oxidases by genetically encoding a metal-ligating unnatural amino acid (bpy-Ala) per protomer in… read more here.
Keywords: dioxygen; synthesis dicopper; dicopper; symmetry ... See more keywords
Iron-Strapped Porphyrins with Carboxylic Acid Groups Hanging over the Coordination Site: Synthesis, X-ray Characterization, and Dioxygen Binding.
Sign Up to like & getrecommendations! Published in 2017 at "Inorganic chemistry"
DOI: 10.1021/acs.inorgchem.7b00343
Abstract: A series of myoglobin active site analogues were synthesized and characterized to investigate the dioxygen binding effects of a flexible distal strap over the coordination site. These four synthetic models differ mostly by the shape… read more here.
Keywords: group; dioxygen; dioxygen binding; ray ... See more keywords
Activation of Dioxygen by a Mononuclear Nonheme Iron Complex: Sequential Peroxo, Oxo, and Hydroxo Intermediates.
Sign Up to like & getrecommendations! Published in 2019 at "Journal of the American Chemical Society"
DOI: 10.1021/jacs.9b05274
Abstract: The activation of dioxygen by FeII(Me3TACN)(S2SiMe2) (1) is reported. Reaction of 1 with O2 at -135 °C in 2-MeTHF generates a thiolate-ligated (peroxo)diiron complex FeIII2(O2)(Me3TACN)2(S2SiMe2)2 (2) that was characterized by UV-vis (λmax = 300, 390,… read more here.
Keywords: mononuclear nonheme; activation dioxygen; me3tacn s2sime2; dioxygen ... See more keywords
Investigation of dioxygen activation by copper(ii)-iminate/aminate complexes.
Sign Up to like & getrecommendations! Published in 2018 at "Dalton transactions"
DOI: 10.1039/c8dt03137a
Abstract: The activation of dioxygen by metal ions is critical in chemical and bio-chemical processes. A scientific challenge is the elucidation of the activation site of dioxygen in some copper metalloproteins, which is either the metal… read more here.
Keywords: dioxygen activation; ligated copper; group; copper ... See more keywords
Syntheses and investigation of metal complexes with macrocyclic polythioether ligands.
Sign Up to like & getrecommendations! Published in 2022 at "Faraday discussions"
DOI: 10.1039/d1fd00062d
Abstract: Copper(I) complexes with the macrocyclic thioether ligands 1,4,8,11-tetrathiacyclotetradecane (tetrathiacyclam, 14-S4) and 1,8-dithia-4,11-diazacyclotetradecane (dithiacyclam, 14-N2S2) were synthesised and structurally characterised. While the copper(I) complexes showed no reactivity towards dioxygen, the formation of "dioxygen adduct complexes" could… read more here.
Keywords: syntheses investigation; dioxygen; metal complexes; investigation metal ... See more keywords
Elemental chalcogen reactions of a tetravalent uranium imidophosphorane complex: cleavage of dioxygen.
Sign Up to like & getrecommendations! Published in 2022 at "Chemical communications"
DOI: 10.1039/d2cc05066h
Abstract: Herein we report the first example of a mononuclear uranium complex, [U4+(NP(pip)3)4] (1-U), that selectively reduces dioxygen to produce a terminal oxo complex, [U6+O(NP(pip)3)4] (2-U; [NP(pip)3]1- is tris(piperidinyl)imidophosphorane). Reactions between 1-U and the heavier elemental… read more here.
Keywords: elemental chalcogen; dioxygen; imidophosphorane; reactions tetravalent ... See more keywords
Iron(II)-α-keto acid complexes of tridentate ligands on gold nanoparticles: the effect of ligand geometry and immobilization on their dioxygen-dependent reactivity.
Sign Up to like & getrecommendations! Published in 2023 at "Dalton transactions"
DOI: 10.1039/d2dt02433k
Abstract: Two mononuclear nonheme iron(II)-benzoylformate (BF) complexes [(6Me2-Me-BPA)Fe(BF)](ClO4) (1a) and [(6Me3-TPMM)Fe(BF)](ClO4) (1b) of tridentate nitrogen donor ligands, bis((6-methylpyridin-2-yl)methyl)(N-methyl)amine (6Me2-Me-BPA) and tris(2-(6-methyl)pyridyl)methoxymethane (6Me3-TPMM), were isolated and characterized. The structural characterization of iron(II)-chloro complexes indicates that the ligand… read more here.
Keywords: immobilization; dioxygen; iron; geometry ... See more keywords