Actinide Triamidoamine (TrenR) Chemistry: Uranium and Thorium Derivatives Supported by a Diphenyl‐tert‐Butyl‐Silyl‐Tren Ligand
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DOI: 10.1002/ejic.202300714
Abstract: We report the synthesis and characterisation of thorium(IV), uranium(III), and uranium(IV) complexes supported by a sterically demanding triamidoamine ligand with N‐diphenyl‐tert‐butyl‐silyl substituents. Treatment of ThCl4(THF)3.5 or UCl4 with [Li3(TrenDPBS)] (TrenDPBS = {N(CH2CH2NSiPh2But)3}3‐) afforded [An(TrenDPBS)Cl] (An = Th, 1Th; U, 1U). Complexes 1An react… read more here.
Keywords: spectroscopy; chemistry; diphenyl tert; ligand ... See more keywords